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How to execute command line and scheduled
When you save session
Click "Save & Make Batch File"
Click "OK", you'll get batch file created, and you can run it in command line, like this:
C: cd "C:\Program Files\RdfToDB2" RdfToDB2.exe session="F:\work\temp\spo.rif" logfile="F:\work\temp\spo.log"
Or click "Create & Schedule Task", you can run this batch file at a specific time and/or at a certain time every day. See this for detail: Schedule Task.